Pre-eruptive magma hybridization and storage conditions recorded in banded pumices from the caldera-forming El Abrigo eruption (Tenerife)
Abstract:
A petrological and geochemical study was carried out on a variety of pumices sampled in the El Abrigo member, ranging from dominantly mafic to banded, and in turn to phonolitic. Banded pumices show a diversity of textures varying from coarsely to finely banded. Mafic scoriae host numerous phonolitic enclaves, sometimes grading to banded within a hand sample. In contrast, phonolitic pumices are homogeneous, almost crystal-free and highly vesicular. Small-scale, fluidal mixing structures are widely present in SEM BSE images and involve the entire compositional spectrum from a partially-crystallized tephriphonolitic composition (SiO2 ~52 wt.%; MgO ~3 wt.%) to a phonolitic melt (SiO2 ~61 wt.%; MgO ~0.3 wt.%). The distribution of fast-diffusing versus slow-diffusing elements indicates that diffusive hybridization has played a significant role. The presence of such small-scale structures and high compositional gradients at scales in the order of tens to hundreds of microns suggest that mixing was of limited efficiency and that the eruption likely started shortly after the beginning of this process, as longer timescales would erase such heterogeneities by advection and chemical diffusion. Several mineral and mineral-melt thermobarometric methods show good agreement and suggest that the mafic end-member had a tephritic composition and was stored prior to the mixing event at ~400 MPa (lowermost oceanic crust) and 1050ºC, and both endmembers contained ~3 wt.% dissolved H2O.