A066
Laboratory Studies in Atmospheric Sciences

Session ID#: 161071

Session Description:
Laboratory studies are fundamental to developing the knowledge needed to understand atmospheric chemistry over a broad range of conditions and environments and applying that knowledge to observations and models of Earth’s atmosphere. This session focuses on laboratory studies in areas including, but not limited to:  gas-phase kinetics (e.g. radical reactions and Criegee intermediates), heterogeneous chemistry (e.g. reactive uptake, interfacial processes), aqueous-phase chemistry (e.g. hydrolysis, photochemistry), chamber studies (e.g. VOC oxidation), spectroscopy (e.g. cross sections, quantum yields), aerosol properties (e.g. SOA formation and aging, nucleation), reaction mechanism development (e.g. isoprene, monoterpenes), and chemistry of the indoor atmosphere. The primary focus is on studies in which the laboratory effort plays a central role in producing scientific results. Presentations on the development of instrumentation and methods that enhance laboratory studies are also encouraged, as are modeling and theoretical studies that incorporate laboratory data or that present results where no laboratory data yet exist.
Index Terms:

0317 Chemical kinetic and photochemical properties [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0340 Middle atmosphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0365 Troposphere: composition and chemistry [ATMOSPHERIC COMPOSITION AND STRUCTURE]
0394 Instruments and techniques [ATMOSPHERIC COMPOSITION AND STRUCTURE]

Primary Convener:  David M Wilmouth, Harvard University, Harvard John A Paulson School of Engineering and Applied Sciences, Cambridge, United States
Conveners:  James B Burkholder, NOAA ESRL, Chemical Sciences Laboratory, Boulder, CO, United States and Neil McPherson Donahue, Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, PA, United States
 
Understanding the Tropospheric Impacts of Isoprene-Derived Carbonyl Oxide Criegee Intermediates: Direct Studies of an Elusive Class of Reactive Intermediates (Invited) (1056326)
Rebecca Caravan, Argonne National Laboratory, Chemical Sciences and Engineering Division, Argonne, IL, United States
 
Development and Validation of a 10-Channel High-Throughput Reactor for the Rapid Study of Pollutant Gas–Surface Interactions (1075282)
Laura C Matchett, Ren Marsh and Sarah A Styler, McMaster University, Department of Chemistry and Chemical Biology, Hamilton, ON, Canada
 
AqSOA Formation from Photosensitized Guaiacol Oxidation: Comparison between Non-phenolic and Phenolic Methoxybenzaldehydes as Photosensitizers in the Absence and Presence of Ammonium Nitrate (1077025)
Set Go Mabato1, Yongjie Li2, Dan Dan Huang3, Yalin Wang2 and Chak K. Chan1, (1)City University of Hong Kong, School of Energy and Environment, Hong Kong, Hong Kong, (2)University of Macau, Department of Civil and Environmental Engineering, and Centre for Regional Ocean, Faculty of Science and Technology, Macau, China, (3)Shanghai Academy of Environmental Sciences, Shanghai, China
 
Real-Time Chemical Characterization of Primary and Aged Organic Aerosols from African Biomass Burning (1079120)
Markie'Sha James, North Carolina A & T State University, Applied Sciences and Technology, Greensboro, United States, Vaios Moschos, North Carolina A&T State University, Department of Physics, Greensboro, United States, Megan Mouton, North Carolina A&T State University, Department of Applied Sciences and Technology, Greensboro, United States, Marc Fiddler, North Carolina A&T State University, Department of Chemistry, Greensboro, United States, Jason D Surratt, University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States and Solomon Bililign, North Carolina A&T State University, Physics, Applied Sciences and Technology, Greensboro, United States
 
Identification of Secondary Organosiloxane Aerosol (SOSA) Using Multiple Mass Spectrometry Techniques (1088253)
Hwajin Kim1, Yanfang Chen2, Hyun Gu Kang3, Jiwoo Jeong2 and Yoojin Park2, (1)Seoul National University, Seoul, Korea, Republic of (South), (2)Seoul National University, Seoul, South Korea, (3)Max Planck Institute for Chemistry, Multiphase Chemistry Department, Mainz, Germany
 
The Optical Properties of African Biomass Fuel-derived Carbonaceous Aerosol Emissions under Different Relative Humidity and Aging Conditions (1091209)
Megan Mouton1, Vaios Moschos2, Marc Fiddler3, Barbara J Turpin4, Jason D Surratt4 and Solomon Bililign5, (1)North Carolina A & T State University, Greensboro, NC, United States, (2)North Carolina A&T State University, Department of Physics, Greensboro, United States, (3)North Carolina A&T State University, Department of Chemistry, Greensboro, United States, (4)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (5)North Carolina A&T State University, Physics, Applied Sciences and Technology, Greensboro, United States
 
Kinetics of Criegee Intermediate Reactions With Carboxylic Acids During Heterogeneous Ozonolysis (1094990)
Ryan Reynolds, University of California Berkeley, Chemistry, Berkeley, United States; Lawrence Berkeley National Laboratory, Chemical Sciences, Berkeley, United States and Kevin R Wilson, Lawrence Berkeley National Laboratory, Chemical Sciences, Berkeley, CA, United States
 
Highly oxygenated organic molecules formation in the oxidation of limonene by OH radical: significant contribution of hydrogen abstraction (1099765)
Hao Luo1, Luc Vereecken2, Hongru Shen1, Iida Pullinen3, Yindong Guo, Sungah Kang5, Mattias Hallquist6, Thomas F Mentel7 and Defeng Zhao1, (1)Fudan University, Department of Atmospheric and Oceanic Sciences & Institute of Atmospheric Sciences, Shanghai, China, (2)Forschungszentrum Jülich, Institute of Energy and Climate Research, Troposphere (IEK-8), Jülich, Germany, (3)Forschungszentrum Jülich, Institute of Energy and Climate Research, IEK-8: Troposphere, Jülich, Germany, (4)Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Troposphere (IEK-8), Jülich, Germany, (5)University of Gothenburg, Department of Chemistry, Atmospheric Science, Gothenburg, Sweden, (6)IEK-8-Troposphere, Juelich, Germany
 
Primary and secondary organic aerosol formation from asphalt pavements (1121688)
Mackenzie Humes1, Jo Machesky2, Drew R Gentner2, Sunhye Kim3, Oladayo Oladeji3, Neil McPherson Donahue1 and Albert Presto4, (1)Carnegie Mellon University, Center for Atmospheric Particle Studies, Pittsburgh, PA, United States, (2)Yale University, Department of Chemical and Environmental Engineering, New Haven, United States, (3)Carnegie Mellon University, Department of Mechanical Engineering, Pittsburgh, United States, (4)Carnegie Mellon University, Department of Mechanical Engineering, Pittsburgh, PA, United States
 
Ozonolysis as an Environmental Loss Process for Emerging Contaminants: Synergistic Effects of Amino, Nitro and Alkene Groups (1129044)
Xinke Wang1, Weihong Wang1, Lisa M Wingen1, Veronique M Perraud1, Michael J Ezell1, Jessica Gable1, Thomas L. Poulos1,2 and Barbara J Finlayson-Pitts1, (1)University of California Irvine, Chemistry, Irvine, United States, (2)University of California Irvine, Molecular Biology and Biochemistry, Irvine, United States
 
Inlet Ionization Mass Spectrometry of Organic Particles: A Soft Method for Probing the Molecular Composition of Surface Layers (1129489)
Yiming Qin, Lisa M Wingen, Veronique M Perraud and Barbara J Finlayson-Pitts, University of California Irvine, Chemistry, Irvine, United States
 
Chamber Studies of the Products and Mechanism of Dimethyl Sulfide Oxidation (1144424)
Jesse H Kroll1, Qing Ye1,2, Matthew Goss1, Jordan Krechmer3, Francesca Majluf3, Alexander Zaytsev4, Yaowei Li4, Joseph R Roscioli5, Manjula R Canagaratna3, Frank N Keutsch4 and Colette L Heald1, (1)Massachusetts Institute of Technology, Civil and Environmental Engineering, Cambridge, United States, (2)National Center for Atmospheric Research, Boulder, United States, (3)Aerodyne Research Inc., Billerica, United States, (4)Harvard University, School of Engineering and Applied Sciences, Cambridge, United States, (5)Aerodyne Research, Inc., Billerica, United States
 
Investigation of Daytime Chemistry of Anthropogenic Volatile Organic Compounds for Different Levels of Nitric Oxide in the Atmospheric Simulation Chamber SAPHIR (1144546)
Michelle Färber, Philip Carlsson, Hendrik Fuchs, Georgios Gkatzelis, Franz Rohrer, Sergej Wedel, Andreas Wahner, Astrid Kiendler-Scharr and Anna Novelli, Forschungszentrum Jülich, Institute of Energy and Climate Research, Troposphere (IEK-8), Jülich, Germany
 
Properties of secondary organic aerosol formation from anisole and possible associated health effects (1146186)
Yinon Rudich1, Chunlin Li2, Michal Pardo2, Alexander Laskin3, Chen Jianmin4,5 and Maria V Misovich6, (1)Weizmann Institute of Science, Earth and Planetary Sciences, Rehovot, Israel, (2)Weizmann Institute of Science, Rehovot, Israel, (3)Purdue University, Department of Chemistry, West Lafayette, IN, United States, (4)Jmchen@Fudan.Edu.Cn, Shanghai, China, (5)Fudan University, Shanghai, China, (6)Purdue University, West Laffayette, United States
 
Solar Zenith Angle and Environmental Dependence of Brown Carbon Photodegradation (1146938)
Greg Drozd1, Lydia Gargano2 and Katherine Brown2, (1)Colby College, Chemistry, Waterville, ME, United States, (2)Colby College, Chemistry, Waterville, United States
 
Hygroscopic and mass measurements of single sea salt aerosol particles using optical trapping (1157065)
Oliver Reich1, Michael Gleichweit1, Grégory David1, Nicole Leemann2 and Ruth Signorell1, (1)ETH Zurich, Chemistry and Applied Biosciences, Zurich, Switzerland, (2)ETH Zurich, Zurich, Switzerland
 
Oxidative Aging of Isoprene Epoxydiol-Derived Secondary Organic Aerosol Under Varying Relative Humidity Conditions (1159614)
Alison Fankhauser1, Madeline Cooke2, Jin Yan3, Rebecca Parham4, Cara Waters5, N. Cazimir Armstrong3, Yao Xiao5, Katherine Kolozsvari5, Weiyu Chen4, Zhenfa Zhang3, Avram Gold3, Jason D Surratt3 and Andrew P Ault2, (1)University of Michigan Ann Arbor, Ann Arbor, MI, United States, (2)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, MI, United States, (3)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (4)University of Michigan Ann Arbor, Ann Arbor, United States, (5)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, United States
 
Isotopic characterization of heterogeneous HONO chemistry (1159646)
Jiajue Chai, Brown University, Department of Earth, Environmental and Planetary Sciences, and Institute at Brown for Environment and Society, Providence, RI, United States, Danielle E. Blum, Brown Univeristy, Department of Chemistry, Providence, United States, Meredith Galanter Hastings, Brown University, Department of Earth, Environmental and Planetary Sciences, and Institute at Brown for Environment and Society, Providence, United States and Evan Donnachie, Brown University, Department of Earth, Environmental and Planetary Sciences, Providence, United States
 
Organosulfate Formation in Proxies for Aged Sea Spray Aerosol: Reactive Uptake of Isoprene Epoxydiols to Acidic Sodium Sulfate (1160492)
Madeline Cooke1, N. Cazimir Armstrong2, Alison Fankhauser3, Katherine Kolozsvari4, Cara Waters4, Rebecca Parham5, Jin Yan2, Ziying Lei6, Yuzhi Chen7, Yue Zhang8, Nicolas A. Buchenau2, Isabel Ledsky9, Jamy Lee10, Avram Gold2, Zhenfa Zhang2, Jason D Surratt2 and Andrew P Ault1, (1)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, MI, United States, (2)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (3)University of Michigan, Ann Arbor, United States, (4)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, United States, (5)University of Michigan Ann Arbor, Ann Arbor, United States, (6)University of Michigan, Department of Environmental Health, Ann Arbor, MI, United States, (7)University of North Carolina at Chapel Hill, Chapel Hill, NC, United States, (8)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, MA, United States, (9)Carleton College, Northfield, United States, (10)University of Michigan, Ann Arbor, MI, United States
 
Experimental Characterization of Cyclic Siloxane Oxidation with Hydroxyl Radicals, Oxidation Flow Reactor (OFR) Results. (1166042)
Saeideh Mohammadi1, Benjamin McMillan2, Nathaniel Massa2, Jeewani Meepage2, Josie Welker2, Elizabeth A. Stone3, Rachel F Marek1, Keri C Hornbuckle1, Christopher Brunet2 and Charles O Stanier4, (1)University of Iowa, Iowa City, IA, United States, (2)University of Iowa, Iowa City, United States, (3)University of Iowa, Department of Chemical and Biochemical Engineering, Iowa City, IA, United States, (4)IIHR—Hydroscience and Engineering, Iowa City, IA, United States
 
Synergistic Effects of Isoprene and HOx on Biogenic New Particle Formation (1170095)
Lee Tiszenkel1, Yue Zhao2, Asadullah Shoaib3, Sameera White3, Yue Zhang4 and Shanhu Lee5, (1)University of Alabama in Huntsville, Atmospheric Science, Huntsville, AL, United States, (2)Shanghai Jiao Tong University, School of Environmental Science and Engineering, Shanghai, China, (3)University of Alabama Huntsville, Huntsville, United States, (4)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, MA, United States, (5)University of Alabama in Huntsville, Huntsville, United States
 
Raman Microspectroscopy of Individual IEPOX-derived Secondary Organic Aerosol Particles After OH Oxidation (1176738)
Weiyu Chen1, Alison Fankhauser2, Jin Yan3, Madeline Cooke4, Cara Waters2, Rebecca Parham2, N. Cazimir Armstrong3, Yao Xiao2, Katherine Kolozsvari2, Zhenfa Zhang3, Avram Gold3, Jason D Surratt3 and Andrew P Ault4, (1)Oberlin College, Department of Geology, Oberlin, United States, (2)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, United States, (3)University of North Carolina at Chapel Hill, Department of Environmental Sciences and Engineering, Chapel Hill, United States, (4)University of Michigan Ann Arbor, Department of Chemistry, Ann Arbor, MI, United States
 
Freezing Temperatures of Lab-Simulated and Real Rainwater Samples (1177597)
Michael Larsen1,2, Lili F Boss1, Griffin P. Hall1, Matthew E Rhodes3 and Matthew Rutter4, (1)College of Charleston, Physics and Astronomy, Charleston, United States, (2)Michigan Technological University, Physics, Houghton, United States, (3)College of Charleston, Biology, Charleston, SC, United States, (4)College of Charleston, Biology, Charleston, United States
 
Surface-Area Inspired Improvements to Ice Nucleation Rate Estimates (1180112)
Michael Larsen1,2, Griffin P. Hall1, Lili F Boss1 and Will H Cantrell3, (1)College of Charleston, Physics and Astronomy, Charleston, United States, (2)Michigan Technological University, Physics, Houghton, United States, (3)Michigan Technological University, Atmospheric Sciences Program, Houghton, MI, United States
 
Laboratory Studies of Atmospheric Photochemistry using Ion Imaging (Invited) (1180483)
Simon W North, Texas A&M University, College Station, TX, United States
 
Development of a Secondary Reaction Chamber for the Study of the Oxidation of Marine VOC Emissions from the Scripps Ocean-Atmosphere Research Simulator (SOARS) (1181419)
Lucia Cancelada1, Dale Stokes2, Greg Sandstrom2, Alexia N Moore1 and Kimberly A Prather1,2, (1)University of California San Diego, Department of Chemistry & Biochemistry, La Jolla, United States, (2)University of California San Diego, Scripps Institution of Oceanography, La Jolla, United States
 
Exploring Secondary Aerosol Formation from Dimethyl Sulfide (DMS) through Gas- and Aqueous-phase Oxidation (1183676)
Ningjin Xu1, Yumeng Cui2, Michael Lum2, Ying Zhou1, Roya Bahreini2, Ying-Hsuan Lin2 and Don Collins1, (1)University of California Riverside, Chemical and Environmental Engineering, Riverside, United States, (2)University of California Riverside, Environmental Sciences, Riverside, United States
 
Pollutant photodegradation by titanium-containing minerals varies with mineral identity and source (1189379)
Alexandra Burnett1, Sarah A Styler1 and Maya Abou-Ghanem2, (1)McMaster University, Department of Chemistry and Chemical Biology, Hamilton, ON, Canada, (2)NOAA Earth System Research Laboratory, Chemical Sciences Division, Boulder, United States
 
Atmospheric Aqueous Phase Reactivity Of Organosulfates (1191288)
Sarah A Styler, McMaster University, Department of Chemistry and Chemical Biology, Hamilton, ON, Canada and Daniel Gweme, McMaster University, Department of Chemistry & Chemical Biology, Hamilton, ON, Canada
 
Uptake Kinetics of a Pure α-pinene-derived Hydroxy Nitrate onto Seed Aerosol at Different Relative Humidity and Particle Acidity. (1194787)
Allison Kawasaki, University of California San Diego, La Jolla, CA, United States, Benjamin A Carr, University of California San Diego, Chemistry and Biochemistry, La Jolla, CA, United States and Jonathan H Slade, University of California San Diego, Chemistry and Biochemistry, La Jolla, United States
 
Effect of Transport Phenomena on the Heterogeneous Oxidation of Aqueous Organic Aerosols. (1198273)
Tadini Wenyika Masaya, West Virginia University, Morgantown, WV, United States
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