| Nafion/Zeolite Nanocomposite Membrane for Direct Methanol Fuel Cell | ||
| Zhongwei Chen, University of California, Riverside, A242 Bourns Hall, Chemical Engineering, Riverside, CA 92507, Brett A. Holmberg, University of California, Riverside, Bourns Hall A242, Riverside, CA 92507, Wenzhen Li, Chemical and Environmental Engineering, University of California, Riverside, Bourns Hall A242, Riverside, CA 92521, Xin Wang, Department of Chemical and Environmental Engineering, University of California, Riverside, Department of Chemical and Environmental Engineering, University of California, Riverside, Riverside, CA 92507 and Yushan Yan, University of California, Riverside, Chemical and Environmental Engineering, 900 University Avenue, Riverside, CA 92521 Nafion/zeolite nanocomposite membranes have been fabricated by in situ hydrothermal growth of acid functionalized zeolite Beta (AF-Beta) nanocrystals into commercial Nafion membranes for direct methanol fuel cells (DMFCs). The presence of zeolite nanocrystals in the composite membrane is confirmed by energy-dispersive X-ray analysis (EDAX) and X-ray diffraction (XRD). Scanning Electron Microscopy (SEM) and Transmission Electron Microscopy (TEM) were used to show the homogeneous composite membrane structure. The physicochemical properties of all membranes were studied regarding their tensile strength, water uptake and thermogravimetric analyzer (TGA). Compared with Nafion membrane, the composite membrane has slightly lower (about 3% reduction) proton conductivity, but much lower methanol permeability (about 40% reduction). The performance of DMFC with Nafion/AF-Beta composite membrane shows much higher (14%) OCV and 25% increase in maximum power density compared with Nafion commercial membrane. The new nanocomposite membrane is a promising candidate for DMFC applications. Extended Abstract Status: Not Uploaded | ||