Fractal Gelation or Self-Preservation
Frank O. Ernst and Sotiris E. Pratsinis, Particle Technology Laboratory, ETH Zürich, Sonneggstrasse 3, ML2 F13, Zürich, 8092, Switzerland

Commonly used rates for turbulence-induced coagulation are extended to non-spherical fractal like particles. The coagulation kernel homogeneity is used to predict gelation and self-preservation for various mechanisms of turbulence-induced coagulation and verified by detailed sectional simulations. For spherical particles, self-preserving distributions are attained in the inertial regime (dp >> η) while coagulation by accelerative mechanisms like fluid fluctuation or gravity in the viscous regime (dp << η) leads to slow gelation as well as shear-induced coagulation in the viscous regime. Non-sphericity or decreasing fractal dimension of particles shift the overall coagulation behavior towards gelation where only coagulation in the inertial regime shows self-preserving behavior.

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Particle Technology Forum Poster Session

The Preliminary Program for 2005 Annual Meeting (Cincinnati, OH)