Friday, 4 November 2005 - 2:45 PM
611h

The Heat of Condensation of Supercooled D2O

Shinobu Tanimura1, Barbara E. Wyslouzil1, Mark Zahniser2, Joanne Shorter2, David Nelson2, and Barry McManus2. (1) Chemical and Biomolecular Engineering, The Ohio State University, 140 W 19th Avenue, Columbus, OH 43210, (2) Aerodyne Research Inc, 45 Manning Road, Billerica, MA 01821

We used a tunable diode laser absorption spectrometer and a static pressure probe to follow changes in the temperature, vapor phase concentration of D2O, and static pressure during condensation in a supersonic nozzle. Using the measured static pressure ratio p/p0 and mass fraction of condensate g as inputs to the diabatic flow equations, we determined the centerline temperature of the flow during condensation. The temperature derived this way is reasonably sensitive to the values assumed for the heat of condensation of D2O. After correcting for the temperature gradient across the boundary layers, the temperature determined from p/p0 and g agreed with the temperature determined by the laser absorption measurements within our experimental error (±2 K). It is the agreement between the two separate temperature measurements that lets us constrain the temperature dependence of the heat of condensation of supercooled D2O down to 210 K.

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