Friday, 4 November 2005 - 1:50 PM
611e

Scaling of Energy Landscape Features in Stressed Systems and Relationship to Viscoelastic Processes

Dan Lacks, Case Western Reserve University, Dept. of Chemical Engineering, Cleveland, OH 44106 and Craig Maloney, Dept. of Physics, University of California Santa Barbara, Santa Barbara, CA.

The stress induced changes in the nature of reaction paths between energy minima and saddle points are characterized. In particular, molecular simulations are used to examine barrier heights and positions, relevant curvatures of the landscape, and directions of reaction paths, for diffusive events. The simulation results on a range of systems, and an associated analytical analysis, show that these features of the energy landscape follow universal scaling laws as the system is stressed. Implications of these scaling laws in regard to viscoelastic processes are discussed.

See more of #611 - Supercooled Liquids and Glasses (01A04)
See more of Engineering Sciences and Fundamentals

See more of The 2005 Annual Meeting (Cincinnati, OH)