Tuesday, 1 November 2005 - 5:00 PM
253h

Linear and Non-Linear Microrheology of Colloidal Suspensions

Eric M. Furst1, Alexander Meyer2, and Myung Han Lee2. (1) University of Delaware, Department of Chemical Engineering, 150 Academy Street, Newark, DE 19716, (2) Department of Chemical Engineering, University of Delaware, Colburn Laboratory, 150 Academy Street, Newark, DE 19716

The microrheology of colloidal suspensions are measured using laser tweezers. Suspensions of index-matched fluorescent silica and fluorinated ethylene propylene (FEP) are seeded with index-mismatched melamine and polystyrene probe particles, respectively. The probes are trapped with laser tweezers and subjected to a uniform flow, enabling measurements of the suspension microviscosity. Good agreement is found between the microviscosities of FEP measured with laser tweezers and bulk viscosities using a couette cell. As the probe size approaches the suspension particle size, non-linear behavior similar to shear thinning is observed at suspension volume fractions ~ 0.23. This is consistent with the formation of a ``wake'' in the non-equilibrium pair distribution function of the suspension surrounding the probe particle [1], which is confirmed by confocal images of probe experiments in fluorescent silica suspensions.

[1.] T. M. Squires, J. F. Brady, Physics of Fluids [submitted].


See more of #253 - Colloidal Hydrodynamics (01J03)
See more of Engineering Sciences and Fundamentals

See more of The 2005 Annual Meeting (Cincinnati, OH)