Thursday, 3 November 2005 - 1:10 PM
491c

A Comparative Study of N-Octane Aromatization over Modified Mfi- and Mel-Type Zeolite Catalysts

Tanate Danuthai1, Siriporn Jongpatiwut1, Thirasak Rirksomboon1, Somchai Osuwan1, and Daniel E. Resasco2. (1) Petrochemical Technology, The Petroleum and Petrochemical College, Chulalongkorn University, Soi Chula 12, Phyathai Rd., Patumwan, Bangkok, 10330, Thailand, (2) School of Chemical, Biological, and Materials Engineering, University of Oklahoma, 100 East Boyd St, Norman, OK 73019

The aromatization of n-octane was studied over modified MFI-(ZSM-5) and MEL-(ZSM-11) type zeolite catalysts as bifunctional catalysts to investigate the effect of pore geometry on their catalytic activity and product distribution. ZSM-5 and ZSM-11 zeolites were synthesized by the conventional method and characterized by using XRD, SEM, and surface area analyzer. Zinc was loaded into the synthesized zeolites by ion exchange to prepare Zn/HZSM-5 and Zn/HZSM-11 catalysts which were then tested for aromatization at 500ºC under atmospheric pressure. Preliminary results revealed that Zn loaded into both zeolites provided a significant increase in total aromatics selectivity. The n-octane aromatization activity for such catalysts was found in the order of Zn/HZSM-5 > Zn/HZSM-11 > HZSM-5 > HZSM-11. This suggests that the aromatization of n-octane takes place preferentially in zigzag channels of ZSM-5 more than in straight channels of ZSM-11. Toluene was observed as a major product, followed by C8-aromatics and benzene on all the catalysts tested.


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