| Base-Catalyze Hydrolysis of Teos in Ethanol | ||
| Janill Castillo and David L. Green, Department of Chemical Engineering, University of Virginia, 102 Engineers Way, Charlottesville, VA 22904 Abstract GOAL: To examine and modify the surface properties of silica nanoparticles. Because silica is widely used in a variety of high-tech applications such as in polymer nanocomposites, semiconductor polishing, or consumer products, controlling the surface properties of silica will govern how the particles will be stable and disperse or unstable and aggregate. Particle stability affects the intended use of the resulting products. Particles were synthesized through base-catalyzed hydrolysis of tetraethylorthosilicate (TEOS). The stability of these unmodified silica particles were studied in water. These particles were modified through esterification with 1-Pentanol. Ultimately, these particles are being grafted with poly(dimethylsiloxane),or PDMS. Particle sizes were quantified with scanning electron microscopy (SEM) and dynamic light scattering (DLS); particle charge was characterized by zeta potential measurements; and particle surface chemistry was studied with Fourier transform infrared spectroscopy (FTIR). Extended Abstract Status: Not Uploaded | ||