Compressed Liquid Densities for Binary Mixtures of n-Hexane + n-Decane and n-Heptane + n-Decane From 313 to 363 K

Friday, November 13, 2009: 9:50 AM
Cheekwood A (Gaylord Opryland Hotel)

Luis A. Galicia-Luna, INSTITUTO POLITECNICO NACIONAL-ESIQIE, Mexico, Mexico
Octavio Elizalde-Solis, Ingeniería Química Petrolera, INSTITUTO POLITECNICO NACIONAL-ESIQIE, Mexico, Mexico
Rodolfo Quevedo-Nolasco Sr., Laboratorio de Termodinámica, ESIQIE, Politécnico Nacional, Mexico, D.F., Mexico
Jose Domenzain-Gonzalez, INSTITUTO POLITECNICO NACIONAL-ESIQIE, Mexico, Mexico

Abstract

PñT properties in the compressed liquid phase were determined for n-hexane + n-decane and n-heptane + n-decane mixtures at temperatures from 313 to 363 K and pressures up to 25 MPa. A vibrating tube densimeter (VTD) was used to measure these densities. The classical calibration method based on two reference fluids (water and nitrogen) was used for the calibration of the VTD. The experimental densities for each n-alkane were in agreement with those reported in literature as expected. A 6-parameter Equation was used to correlate the mixture densities. This equation represents data within the experimental uncertainty of 0.2 kg/m3.

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See more of this Session: Experimental Phase Equilibria and PVT I
See more of this Group/Topical: Engineering Sciences and Fundamentals