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Isobaric Vapor-Liquid Equilibrium of 1-Propanol and Benzene System


Dong-Yuk Kang, Department of Advanced Chemicals and Engineering, Chonnam National University, Gwangju, South Korea
Hoi-Gu Jang, Department of Advanced Chemicals and Engineering, Chonnam National University, Gwangju, South Korea
Chang-Nam Han, Department of Advanced Chemicals and Engineering, Chonnam National University, Gwangju, South Korea
Dong Lyun Cho, Department of Advanced Chemicals and Engineering, Chonnam National University, Gwangju, South Korea
Choon-Hyoung Kang, Applied Chemical Engineering Department and the Research Institute for Catalysis, Chonnam National University, Kwangju, South Korea

In this study, isobaric vapor-liquid equilibria of a binary mixture of 1-propanol and benzene, which shows severe nonideal behavior with azeotropic compositions, were measured by using a recirculating equilibrium cell from Illudest at various pressures ranging from 20kPa to 70kPa. The measured VLE data were satisfactorily correlated with UNIQUAC and NRTL models along with the thermodynamic consistency test. The excess molar volume of the mixture was also measured using a vibrating densitometer.
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