This preliminary program is subject to change.

Solvents for Gas Separation


Description:
Solvents can be used to separate single or multiple components from a gas stream. Depending on the application, physical or chemical solvents can be used. In power generation, fossil fuels can be combusted to form a flue gas and this is currently the most dominant technique for production of electricity. Fossil fuels could also be gasified to form carbon monoxide and hydrogen, called fuel, synthesis, or syngas, and this gas can be combusted in an integrated gasification-combined-cycle scheme to produce energy or it can be used as a building block for the production of chemicals. In either the combustion or gasification processes, various compounds/elements may be required by current regulations (e.g., mercury) or future regulations (e.g., carbon dioxide) to be removed from the gas streams. Depending on the specific scenario, hydrogen sulfide, carbon dioxide, mercury, and/or other trace components could be removed from the gas stream by a solvent. Although commercial techniques do exist, novel evolutionary and revolutionary concepts are being developed that can separate gaseous components from post-combustion and pre-combustion streams. Presenters are encouraged to submit experimental and computational approaches for solvent gas separation. Additionally, although gas stream cleanup for post-combustion and gasification applications are of interest, other novel solvent techniques related to fossil energy can be submitted, such as oxygen separation from air, cleanup of natural gas, etc.

Sponsor:
Gas Separation
Co-Sponsor(s):
Accelerating Fossil Energy Technology Development Through Integrated Computation and Experimentation (TD), ICE2012: Fossil Fuels & CCS (T4G)


Chair:
Robert M. Enick
NETL RUA Professor
University of Pittsburgh
Dept. of Chemical and Petroleum Engineering
Pittsburgh, PA 15261
Fax Number: 412-624-9639
Email: rme@pitt.edu


Papers:
New Experimental Data and Physico-Chemical Model for the Solubility of Carbon Dioxide in Aqueous Solutions of Monoethanolamine
Michael Wagner, University of Kaiserslautern; Inga von Harbou, University of Kaiserslautern; Jaeik Kim, University of Kaiserslautern; Gerd Maurer, University of Kaiserslautern; Hans Hasse, University of Kaiserslautern
Mass Transfer Evaluation of CO2 Absorption in a Wetted Wall Column
Reynolds A. Frimpong, Center for Applied Energy Research, University of Kentucky; Joseph E. Remias, University of Kentucky; James K. Neathery, University of Kentucky; Kunlei Liu, University of Kentucky
Aqueous Morpholine As a Potential Post-Combustion CO2 Absorption Solution
Krishna Mohan Jinka, University of Kentucky; Taylor Kuhn, University of Kentucky; Joseph E. Remias, University of Kentucky; James K. Neathery, University of Kentucky; Kunlei Liu, University of Kentucky
Novel Liquid-Like Nanoscale Organic Hybrid Materials for CO2 Capture
Camille Petit, Columbia University; Youngjune Park, Columbia University; Kunyi Andrew Lin, Columbia University; Ah-Hyung Alissa Park, Columbia University
Development of Reaxff Force Field for Carbon Dioxide Capture with Ionic Liquids: A Combined First Principles and Classical Simulation
Bo Zhang, US DOE-National Energy Technology Laboratory; Adri C.T. van Duin, Pennsylvania State University; Karl Johnson, University of Pittsburgh
Vibrational Spectroscopy Characterization of CO2-Ionic Liquid Systems for Pre-Combustion CO2
Anita S. Lee, Carnegie Mellon University; John R. Kitchin, Carnegie Mellon University