344108 Compressed Liquid Densities for the Ethanol + Heptane + Decane System At High Pressures and Temperatures

Monday, November 4, 2013
Grand Ballroom B (Hilton)
Héctor S. Zamora-López, Laboratorio de Termodinámica - SEPI, Instituto Politécnico Nacional - E.S.I.Q.I.E., Mexico, D. F., Mexico, Luis A. Galicia-Luna, INSTITUTO POLITECNICO NACIONAL-ESIQIE, Mexico, Mexico and Octavio Elizalde-Solis, Departamento de Ingeniería Química Petrolera, INSTITUTO POLITECNICO NACIONAL-ESIQIE, México, D. F., Mexico

Thermodynamic behavior of ternary systems has been studied in the last decades. In this work, volumetric properties for the ternary system x1 ethanol + x2 heptane + (1-x1-x2) decane are reported in the range of temperature of (313 to 363) K and pressures up to 20 MPa. The experimental apparatus is based on the static – synthetic method coupled to a commercial vibrating tube densimeter from Anton Paar. Experimental densities are reported within an uncertainty of 0.2 kg·m-3. Deviations between experimental and calculated values agree and are within the experimental uncertainty. Compositions for the ternary system were prepared keeping constant the heptane/decane relation and by varying of ethanol. Density results were correlated using an empirical model with 5 parameters.

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