394917 Self-assembly, self-organization, and the design of new materials

Sunday, November 16, 2014
Galleria Exhibit Hall (Hilton Atlanta)
William Benjamin Rogers, School of Engineering and Applied Sciences, Harvard, Boston, MA

My research focuses on understanding and controlling the self-assembly and self-organization of nanoparticle-based materials, which find applications ranging from photonics and plasmonics to industrial formulations such as coatings. A central aim of my work is to develop quantitative design strategies for controlling dynamic pathways to self-assembly. At the intersection of physics and engineering, this research utilizes synthetic chemistry, advanced imaging techniques, micromanipulation, and statistical physics. I will discuss the development of a suite of non-equilibrium pathways to self-assembly that are implemented using DNA reaction networks, including self-limiting growth of finite-sized structures, assembly of novel periodic lattices due to specific next-nearest-neighbor interactions, and design of smart materials that can reconfigure themselves in response to an external cue. These pathways can be understood quantitatively using core chemical-engineering concepts, including chemical kinetics and reaction engineering, transport, and thermodynamics.

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