484933 Liquid-Liquid Extraction: Last but Not Least

Timothy Threatt1, Jacob H. Arredondo1 and Jonathan H. Worstell2, (1)Chemical Engineering, Rice University, Houston, TX, (2)Worstell and Worstell, Consultants, Richmond, TX

When we ask chemical engineering students to list equilibrium stage-wise processes, distillation is the first such process on the list, followed by stripping, then, maybe, absorption. They generally don’t list liquid-liquid extraction. What is the reason for this over-sight? First, it comes late in a Unit Operations semester; thus, if the course falls behind the course calendar, it gets dropped. Second, liquid-liquid extraction involves the use of phase diagrams to calculate the number of equilibrium stages for a process; hence, considerable effort must be expended teaching their use and the arcane mathematics required for the calculation. Third, there are no simple liquid-liquid extraction experiments from which students can gain hands-on experience. Taken in toto, most graduating B.S. Chemical Engineers have little knowledge of liquid-liquid extraction.

This presentation investigates liquid-liquid extraction heuristically; i.e., using dimensional analysis. It also discusses a simple, inexpensive laboratory experiment that highlights the pertinent concepts of a dimensional analysis of liquid-liquid extraction.


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