503523 Interpenetrating Networks for Flexible Bulk Heterojunction Opvs

Jorge Mok1, Zhiqi Hu2 and Rafael Verduzco1, (1)Chemical and Biomolecular Engineering, Rice University, Houston, TX, (2)Chemical and Biomolecular Eng, Rice University, Houston, TX

Bulk heterojunction organic photoltaic (OPV) devices can be fabricated fully though solution processing on a variety of substrates, but the active layer typically exhibits very poor flexibility and robustness in response to strains and deformation. Here, we present a general approach to fabricating flexible bulk heterojunction OPVs through the incorporation of an interpenetrating polymer network. We show that this provides P3HT/PCBM bulk heterojunction OPVs that are fully flexible and able to sustain stresses in excess of 50 %. Small molecular OPV blends are more robust, and we flexible OPV devices with power conversion efficiencies exceeding 5 % power conversion efficiencies.

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See more of this Session: Conjugated Polymers
See more of this Group/Topical: Materials Engineering and Sciences Division