475951 Hyperpure Urea Crystal Preparation and Morphology Control for the Adbule Manufacture

Thursday, October 27, 2016: 10:15
Pan Li1, Xiaobin Jiang2 and Gaohong He2, (1)Dalian University of Technology, Dalian, China, (2)Dept. of Chemical Engineering, Dalian University of Technology, Dalian, China

Abstract

AdBlue, a hyperpure urea solution used for removal of NOx in diesel powered vehicles is widely available throughout the world. To maintain the efficiency of the catalyst, the impure metal ions should be strictly controlled.[1,2] In this work, the industrial grade urea is purified by the controlled suspension melt and cooling crystallization.[3] The metastable zone width of urea crystal was measured.[4,5] The crystal morphology control strategy was developed to obtain a rubust preparation route. With the optimized operation curve, the aspect ratio decreased from 8.5 to 4.5 and the quantity of urea crystal had been well controlled.

References

[1] Shen B. J. Ind. Eng. Chem., 2016, 33:262-269.

[2] Fernandez N. Chem. Eng. J., 2016,285:77-82.

[3] Jiang X., Xiao W. et al. Chem. Eng. Sci. 2014, 117: 198-209.

[4] Titiz S,Ulrich J. Cryst. Growth Des., 2004, 2:371-374.

[5] Jiang X., Xiao W. et al. Chem. Eng. Sci. 2015, 134: 671-680.


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