Ion Exchange Resins for Biodiesel Purification
Daryl J. Gish, Larkin Laboratory, The Dow Chemical Company, Midland, MI 48674

Specialty ion exchange resins can be utilized to bind and remove trace impurities from a biodiesel process stream. After the bulk separation of the glycerin, the biodiesel stream is simply passed though a column of the dried ion exchange resin to bind and remove both ionic salts (such as Na+ and Ca++0, trace catalysts, soaps, and glycerin. The dried resin also acts as a desiccant retaining and removing trace water from the biodiesel feed.

The efficiency and life of a resin to reduce and remove impurities from the biodiesel will depend upon how well bulk separation of the biodiesel and glycerin are made. A resin operation step should be viewed as a polishing process to remove trace materials in the 275-750ppm range, not as a replacement for optimizing the bulk separation.

Generally a lead-lag two column continuous feed system is recommended for most operations. In many cases, a third column should be considered in order to ensure continuous operations and reduce down times. Specialty ion exchange resins, like the DOWEX(TM) DR-G8 resin can be applied to improve and enable a producer to meet ASTM or EN specifications at the point of production to reduce rework and lessen blending concerns.

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