- 3:15 PM
98d

Conversion of Pyrolysis Oil

Teerawit A. Prasomsri, Roberto E. Galiasso, Lance L. Lobban, Richard G. Mallinson, and Daniel E. Resasco. School of Chemical, Biological and Materials Engineering, University of Oklahoma, 100 E Boyd St., SEC, T-335, Norman, OK 73019

1- and 2- tetralones are used as the representative compound in biomass-derived pyrolysis oil (or bio-oil). This work focused on conversion of oxygenated aromatic compounds over HY zeolite. The reactions were conducted in fixed-bed reactor at 300, 400 and 500 ºC under hydrogen atmospheric pressure. Pure feeds were introduced to the reactor by using a bubbler in order to minimize condensation or solvent problems. It was found that 2-tetralone is thermally unstable and has a higher reactivity than 1-tetralone. Gaseous products were analyzed by on-line GC. Hydrogen abstraction (i.e. naphthol product) and coupling (i.e. heavies) were the main reaction paths. Deoxygenation (i.e. to tetralin and naphthol) products was a slower path.