Laser Annealing of Amorphous Ni-Ti Shape Memory Alloy Thin Films
Mr. Xi Wang1, Prof. Yves Bellouard2, Dr. Zhenyu Xue1 and Prof. Joost J. Vlassak1, 1Division of Engineering and Applied Sciences, Harvard University, 29 Oxford Street, Cambridge, MA 02138, 2Micro- & Nano-Scale Engineering, Mechanical Engineering, Eindhoven University of Technology, PO Box 513, 5600 MB, Eindhoven, Netherlands

We present the results of a crystallization study on NiTi shape memory thin films in which amorphous films are annealed by a scanning laser. Laser annealing makes it possible to spatially distributed shape memory properties in thin-film devices, e.g., amorphous or passive elements can be created in parallel with crystalline or active elements to effect in-plane actuation. A kinetics study shows that nucleation of the crystalline phase occurs homogenously in the films. Consequently, the laser annealing process produces polycrystalline films with a random crystallographic texture. The crystallized films have a uniform microstructure across the annealed areas. The material in the crystalline regions transforms reversibly to martensite on cooling from elevated temperature and stress measurements show that a significant recovery stress is achieved in the films upon transformation. Temperature profiles induced in the film by the scanning laser were calculated using a full three-dimensional finite element model. The model takes into account oxidation of the NiTi surface and allows prediction of the size of the crystallized regions as a function of laser annealing parameters.

Session 5: Thin Films, Powder, and Porous Materials

The Preliminary Program for The International Conference on Shape Memory and Superelastic Technologies (May 7-11, 2006)