Morphological Characterization and Corrosion Resistance of TiNi Foams Obtained Via SHS Processing for Biomedical Applications
Dr. Luigi de Nardo1, Dr. Francesca Brunella2, Dr. Gianni Rondelli3, Dr. Silvia Farè1, Dr. Peter Jardine4, Dr. Alberto Cigada2 and Dr. L.'Hocine Yahia5, 1BioMatLab - Bioengineering department, Politecnico di Milano, Piazza Leonardo da Vinci 32, Via Golgi 39 - building 34, Milano, 20133, Italy, 2Chemistry Materials and Chemical Engineering "Giulio Natta", Politecnico di Milano, Piazza Leonardo da Vinci 32, Milano, 20133, Italy, 3CNR-IENI, Via Roberto Cozzi 53, Milano, 20125, Italy, 4Shape Change Technologies, E. Hillcrest Drive, Suite 108, Thousand Oaks, CA 91362, 5Biomedical Engineering, Polytechnique de Montréal, 2500, chemin de Polytechnique, Montreal, QC H3C 3A7, Canada

The nearly equiatomic nickel titanium alloys have been widely used in the biomedical device industry because of their unique shape memory, superelasticity, fatigue resistance properties and a stress-strain behavior similar to that of living tissues. Despite of all these advantages, a wider application of these alloys in the biomedical field has been hindered for a long time, owing to the lack of a definite conclusions about its corrosion properties and nickel release.
A new class of TiNi foams, produced via Self-Propagating High-Temperature Synthesis (SHS) method, has found a growing interest in orthopedic devices design.
The present study was undertaken to examine the corrosion resistance and the ion release of TiNi foams, for using them in orthopedic device design. Morphology studies were conducted by picnometer measurements and SEM observations; Corrosion stability was evaluated by electrochemical potentiodynamic and potentiostatic tests. The foams were analyzed as received and treated in nitric acid to improve the surface passivation. Results show that TiNi foams could be promising biomaterials for orthopedic applications.

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