Paper No. 31916-210871
GRAPHITIC CARBONS: PLAYERS AND TRACERS OF GEOLOGICAL PROCESSES

BEYSSAC, Olivier, CNRS IMPMC Paris, Campus Jussieu, Case courrier 115, 4 place Jussieu, Paris, 75005, France, olivier.beyssac@impmc.upmc.fr, GALVEZ, Matthieu E., IMPMC and IPG Paris, 1 rue Jussieu, Paris, 75005, BERNARD, Sylvain, Lmcm Umr 7202 Cnrs, MNHN Paris, Case Postale 52 - 61, rue Buffon, Paris, 75005, France, BENZERARA, Karim, Institut de Mineralogie et de Physique des Milieux Condensés, CNRS & Univ Pierre et Marie Curie, 4 Place Jussieu, Paris, 75005, France, and MARTINEZ, Isabelle, Géochimie des isotopes stables, IPGP, 4 Place Jussieu, Paris, 75005, France
Graphitic (sp2-bonded) carbons are widely present on Earth and in the Universe. They have a complex structural organization ranging from amorphous-like and turbostratic phases to perfectly crystallized graphite. This structure is a legacy of their geological history and is a fingerprint of the physico-chemical conditions that prevailed during their formation. To retrieve complete information, this structure must be characterized from the nm to the µm scale by combining various microscopy (SEM, TEM, STXM…) and spectroscopy (Raman, XANES), together with isotopic geochemistry. Various recent studies involving graphitic carbons will be reviewed such as fossilization and traces of life in high-pressure metamorphic rocks, graphitization during metamorphism (which can serve as a geothermometer), or abiotic graphite formation from carbonate reduction during fluid-rock interactions in subduction. Last, the fate of graphitic carbons during erosion will be discussed as they might be recycled owing to their refractory character, and therefore constitute a carbon sink on geological timescales.
Discipline Categories: Mineralogy/Crystallography, Geochemistry

Preferred Presentation Type: Oral