| Cold Spraying of Refractory Metals - Powder Characteristics and Coating Properties | ||
| Dr. Stefan Zimmermann1, Dr. Hans Keller1, Mr. Tobias Schmidt2, Prof. Heinrich Kreye2 and Mr. Peter Heinrich3, 1Ceramics and Surface Technology, H.C. Starck GmbH, Kraftwerkweg 3, Laufenburg, 79725, Germany, 2Institute of Materials Technology, Helmut-Schmidt-University Hamburg, Holstenhofweg 85, Hamburg, 22043, Germany, 3Linde Gas Division, Linde AG, Carl von Linde Stasse 25, Unterschleissheim, 85716, Germany
In contrast to conventional thermal spray processes, in cold gas spraying coatings are produced without melting of the powder particles. A fundamental precondition for the bonding is a certain ductility of the spray material. The bonding of the particles is based on plastic deformation of the particles at impact and the heat generated thereby. It occurs when a minimum critical particle velocity is reached. This critical velocity does not only depend on the particles´ temperature but mainly on their mechanical and physical properties like density and melting temperature. Due to their high melting temperature and due to the fact that their ductility is essentially impaired by gaseous impurities most refractory metals are comparatively difficult to be applied by cold gas spraying. The present paper reports on the development of tailored refractory metals such as Ta and Nb for cold gas spraying. Under consideration of the latest optimisation of the cold gas systems in terms of particle temperature and velocity, the influence of the chemical and physical properties of the powders on both coating quality and deposition efficiency are described. | ||